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矿物掺合料对混凝土力学性能影响的研究进展

Research Progress on the Influence of Mineral Admixtures on the Mechanical Properties of Concrete

  • 摘要: 节能减排是混凝土行业绿色发展的核心趋势,传统水泥的大量使用既不符合低碳要求,也存在资源过度消耗的压力。矿物掺合料作为固废资源化利用的关键材料,既能降低混凝土的碳足迹,又有望改善其力学性能。为明确矿物掺合料对混凝土力学性能的影响规律及作用机理,选取粉煤灰、硅灰、矿渣粉、稻壳灰、沸石粉五种矿物掺合料,从孔隙结构优化、火山灰反应强化、微观结构调控等维度,解析其对混凝土力学性能的作用机制。研究发现,矿物掺合料可通过细化孔隙、降低有害孔隙占比来优化混凝土孔结构,借助火山灰反应生成水化硅酸钙凝胶,显著提升抗压强度、抗折强度与弹性模量等。不同掺量、颗粒级配、自身活性及预处理方式会改变作用效果(如硅灰早期强度增强效应突出,粉煤灰需调控掺量来平衡早/后期强度发展)。合理调控矿物掺合料的掺量、颗粒级配及复配方案,能够精准适配混凝土力学性能与耐久性的需求,为高性能混凝土的配合比设计与工程应用提供支撑。

     

    Abstract: Energy conservation and emission reduction constitute the core trend of green development in the concrete industry. The extensive use of traditional cement is neither in line with low-carbon requirements nor imposes pressure from excessive resource consumption. As key materials for the resource utilization of solid waste, mineral admixtures can not only reduce the carbon footprint of concrete but also are expected to improve its mechanical properties.To clarify the influence laws and mechanisms of action of mineral admixtures on the mechanical properties of concrete, five types of mineral admixtures, namely fly ash, silica fume, ground granulated blast-furnace slag, rice husk ash, and zeolite powder, were selected, and their mechanisms of action on the mechanical properties of concrete were analyzed from the dimensions of pore structure optimization, pozzolanic reaction enhancement, and microstructural regulation; the study revealed that mineral admixtures can optimize the pore structure of concrete by refining pores and reducing the proportion of harmful pores, and through pozzolanic reactions, they generate calcium silicate hydrate gel, significantly improving properties such as compressive strength, flexural strength, and elastic modulus, while variations in dosage, particle gradation, inherent reactivity, and pretreatment methods alter these effects (e.g., silica fume exhibits a prominent early-age strength enhancement effect, while fly ash requires dosage regulation to balance the early- and late-age strength development); reasonable regulation of the dosage, particle gradation, and composite formulation of mineral admixtures can precisely meet the requirements for the mechanical properties and durability of concrete, providing support for the mix proportion design and engineering application of high-performance concrete.

     

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